My apologies, below is working code:
frappe.ui.form.on('Quotation', {
refresh(frm) {
frm.fields_dict["items"].grid.add_custom_button(__('Hello'),
function() {
frappe.msgprint(__("Hello"));
});
frm.fields_dict["items"].grid.grid_buttons.find('.btn-custom').removeClass('btn-default').addClass('btn-primary');
}
})
